Browsing by Author "Unaleroglu, Canan"

Now showing 1 - 3 of 3

Citation - WoS: 3
Citation - Scopus: 3
N-Phosphorylation of Pyrroles: an Intramolecular Migration Reaction
(Pergamon-elsevier Science Ltd, 2018) Unaleroglu, Canan; Tasgin, Dilek Isik
A new synthetic method is reported for the N-phosphorylation of pyrroles via intramolecular migration of a phosphonate diester group. The reaction proceeds under mild conditions and produces N-phosphorylated pyrrole derivatives in moderate to good yields. (C) 2018 Elsevier Ltd. All rights reserved.
Citation - WoS: 5
Citation - Scopus: 6
Ring Annulation Versus Alkylation of Pyrrole With Α-Phosphoryl Ketones
(Pergamon-elsevier Science Ltd, 2016) Tasgin, Dilek Isik; Unaleroglu, Canan
In this study; novel aryl, heteroaryl, pyrrolyl and phosphoryl groups containing pyrrolizines were synthesized by the ring annulation reaction of aryl or heteroaryl substituted alpha-phosphoryl-alpha,beta-unsaturated ketones with pyrrole under mild reaction conditions. This domino reaction involves scandium triflate catalyzed addition of pyrrole to the double bond of alpha-phosphoryl-alpha,beta-unsaturated ketones, carbonyl group and finally ring annulation sequences. The presented work provided a convenient way for the synthesis of novel bispyrrolic compounds. (C) 2016 Elsevier Ltd. All rights reserved.
Substituent-Controlled Construction of A4b2-Hexaphyrins and A3b-Porphyrins: a Mechanistic Evaluation
(Beilstein-institut, 2023) Cinar, Seda; Tasgin, Dilek Isik; Unaleroglu, Canan
A substituent-dependent construction of novel A3B-porphyrins along with A4B2-hexaphyrins was realized by the reactions of N-tosylimines and meso-aryl-substituted tripyrranes in the presence of Cu(OTf)2 as the catalyst. The reaction mechanism of the presented method was studied on model reactions by electrospray-ionization time-of-flight (HRESI-TOF) mass spectral analysis in a timely manner. The analytical results indicated that the observed azafulvene-ended di- and tripyrrolic intermediates are responsible for the formation of porphyrinogen and hexaphyrinogen forms.