Fizik Bilim Dalı
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12416/1819
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Browsing Fizik Bilim Dalı by browse.metadata.publisher "Elsevier Gmbh"
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Article Citation - WoS: 4Citation - Scopus: 5Calculation of the Raman Frequency, Damping Constant (Linewidth) and the Relaxation Time Near the Tetragonal-Cubic Transition in Pbtio3(Elsevier Gmbh, 2017) Yurtseven, H.; Kiraci, A.Frequencies, damping constants and the relaxation times of some Raman modes including the two soft modes are calculated as a function of pressure near the tetragonal-cubic transition in PbTiO3. Calculation of the Raman frequencies is performed using the observed volume data from the literature by means of the mode Gruneisen parameter at various pressures. Pressure dependence of the damping constant and the relaxation time is predicted using the pseudospin-phonon coupled model and the energy fluctuation model by considering that the Raman frequency can be taken as the order parameter (spontaneous polarization) for the tetragonal-cubic transition in PbTiO3. Expressions from both models for the damping constants are fitted to the observed Raman linewidths of the two soft modes and for the other Raman modes the damping constant and the relaxation time are predicted close to the transition. We find that damping constants diverge and the inverse relaxation time decreases for the soft modes with increasing pressure near the critical pressure (P-c similar to 11 GPa). The other Raman modes exhibit unusual critical behavior. Our results indicate that the observed behavior of the Raman frequencies can be predicted from the volume data through the mode Gruneisen parameter for the tetragonal-cubic transition in PbTiO3. The damping constant and the relaxation time for the Raman modes can also be predicted adequately using the pseudospin-phonon coupled model and the energy fluctuation model to explain the mechanism of the phase transition between the tetragonal and cubic phases in PbTiO3. (C) 2017 Elsevier GmbH. All rights reserved.Article Citation - WoS: 3Citation - Scopus: 3Optical and Photoelectrical Properties of Tlinsse Layered Single Crystals(Elsevier Gmbh, 2018) Gasanly, N.; Guler, I.Optical and electrical properties of TlInSSe layered single crystals have been studied by means of transmission, reflection and photoconductivity measurements. Transmission and reflection experiments have been carried out from 540 to 1000 nm at room temperature. Derivative analysis was applied to both transmission and reflection spectra and indirect band gap energy was found as 2.06 eV. Photoconductivity measurements have been performed in the temperature range from 245 to 300 K and in the voltage range from 10 to 80 V. From the temperature-dependent photoconductivity measurements, the observed single peak shifted to higher wavelengths with increase of temperature. The increase of photoconductivity with temperature is due to the increase in the mobility of photocarriers that can be explained by Bube model. From X112 method, room temperature indirect band gap of the crystal was also found as 2.06 eV. From voltage-dependent photoconductivity measurements, the peak maximum increased linearly with increase of voltage because of increase of the mobility of charge carriers. Dark current-voltage characteristic of TlInSSe crystal showed the ohmic behavior that means space charge limited current did not exist in the crystal. From the photocurrent with different illumination intensity analysis, the supralinear photoconductivity associated with the two center model was found. (C) 2017 Elsevier GmbH. All rights reserved.Article Citation - WoS: 8Citation - Scopus: 8Thermoluminescence in Gallium Sesquisulfide Single Crystals: Usual and Unusual Heating Rate Dependencies(Elsevier Gmbh, 2018) Isik, M.; Gasanova, L.; Mahammadov, A.; Gasanly, N.; Guler, IThermoluminescence (TL) experiments were conducted for Ga2S3 crystals to obtain information about trapping parameters. TL measurements were performed from 10 to 300 K with varying heating rates in the range of 0.2-0.8 K/s. Two TL glow peaks centered at 44K (peak A) and 91 K (peak B) were observed at heating rate of beta=0.5 K/s. For peak A, TL intensity decreased whereas that for peak B increased with elevating the heating rates that means anomalous heating rate occurred for peak B. TL glow curves were analyzed using initial rise method to find activation energies of traps. Distribution of trap centers was investigated using T-max - T-stop method. Quasi-continuous distributions with increasing activation energies from 40 to 135 meV and 193 to 460 meV were attributed to trap centers A and B, respectively. (C) 2018 Elsevier GmbH. All rights reserved.
