Ortak Dersler Bölümü

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Adaptive Estimation of Autoregressive Models Under Long-Tailed Symmetric Distribution
(Association for Computing Machinery, 2019) Yentür, B.; Bayrak, Ö.T.; Akkaya, A.D.
In this paper, we consider the autoregressive models where the error term is non-normal; specifically belongs to a long-tailed symmetric distribution family since it is more relevant in practice than the normal distribution. It is known that least squares (LS) estimators are neither efficient nor robust under non-normality and maximum likelihood (ML) estimators cannot be obtained explicitly and require a numerical solution which might be problematic. In recent years, modified maximum likelihood (MML) estimation is developed to overcome these difficulties. However, this method requires that the shape parameter is known which is not realistic in machine data processing. Therefore, we use adaptive modified maximum likelihood (AMML) technique which combines MML with Huber’s estimation procedure so that the shape parameter is also estimated. After derivation of the AMML estimators, their efficiency and robustness properties are discussed through a simulation study and compared with MML and LS estimators. © 2019 Association for Computing Machinery.
Analysis of the Specific Heat and the Free Energy of [N(Ch 3 ) 4 ] 2 Znbr 4 Close to the Ferro-Paraelastic Phase Transition
(Taylor&Francis LTD, 2019) Kiracı, Ali
A power-law formula deduced from the Ising model was used to analyze the temperature dependence of the specific heat C p and the Gibbs free energy G of [N(CH 3 ) 4 ] 2 ZnBr 4 compound in the vicinity of the phase transition temperature of T C = 287.2 K. Obtained values of the critical exponents α from the Gibbs free energy were consistent with that predicted from 2-d potts model (α = 0.3), while obtained values of α from the specific heat in both ferroelastic and paraelastic phases were consistent with that predicted from the mean field theory (α = 0) in the vicinity of the phase transition temperature. This is an indication of that [N(CH 3 ) 4 ] 2 ZnBr 4 compound undergoes a second order type phase transition. Also, the enthalpy (H) and the entropy (S) of this crystal were calculated in terms of the extracted values of the critical exponent in both ferroelastic and paraelastic phases.
Analysis of the specific heat and the free energy of [N(CH3)(4)](2)ZnBr4 close to the ferro-paraelastic phase transition
(Taylor&Francis LTD, 2019) Kiracı, Ali
A power-law formula deduced from the Ising model was used to analyze the temperature dependence of the specific heat and the Gibbs free energy of [N(CH3)(4)](2)ZnBr4 compound in the vicinity of the phase transition temperature of T-C = 287.2 K. Obtained values of the critical exponents from the Gibbs free energy were consistent with that predicted from 2-d potts model ( = 0.3), while obtained values of from the specific heat in both ferroelastic and paraelastic phases were consistent with that predicted from the mean field theory ( = 0) in the vicinity of the phase transition temperature. This is an indication of that [N(CH3)(4)](2)ZnBr4 compound undergoes a second order type phase transition. Also, the enthalpy () and the entropy () of this crystal were calculated in terms of the extracted values of the critical exponent in both ferroelastic and paraelastic phases.
Citation - WoS: 8
Citation - Scopus: 8
Analysis of the Specific Heat and the Free Energy of [N(ch3)4]2znbr4 Close To the Ferro-Paraelastic Phase Transition
(Taylor & Francis Ltd, 2019) Kiraci, A.
A power-law formula deduced from the Ising model was used to analyze the temperature dependence of the specific heat and the Gibbs free energy of [N(CH3)(4)](2)ZnBr4 compound in the vicinity of the phase transition temperature of T-C = 287.2 K. Obtained values of the critical exponents from the Gibbs free energy were consistent with that predicted from 2-d potts model ( = 0.3), while obtained values of from the specific heat in both ferroelastic and paraelastic phases were consistent with that predicted from the mean field theory ( = 0) in the vicinity of the phase transition temperature. This is an indication of that [N(CH3)(4)](2)ZnBr4 compound undergoes a second order type phase transition. Also, the enthalpy () and the entropy () of this crystal were calculated in terms of the extracted values of the critical exponent in both ferroelastic and paraelastic phases.
Citation - WoS: 1
Citation - Scopus: 1
Calculation of the Frequency Shifts and Damping Constant for the Raman Modes (A1g, B1) Near the Tetragonal-Cubic Transition in Srtio3
(Tubitak Scientific & Technological Research Council Turkey, 2017) Yurtseven, Hasan Hamit; Kiraci, Ali
Raman shifts of the soft mode A(1g) and the B-1 mode are calculated at various pressures at room temperature for the cubic-tetragonal transition (P-c = 9.5 GPa) in SrTiO3. This calculation is performed using the observed volume data through the mode Gruneisen parameters of A(1g) and B-1 which vary with pressure, by fitting to the experimental wavenumbers in this crystalline system. Calculated Raman shifts are then used as order parameters to predict the pressure dependence of the damping constant and the inverse relaxation time for the cubic-tetragonal transition in SrTiO3. Our predictions from the pseudospin-phonon coupling and the energy fluctuation models can be compared with the experimental measurements when available in the literature.
Citation - WoS: 3
Citation - Scopus: 3
Characterization of N Rich-Silicon Nitride Thin Films Deposited by Pecvd
(Electrochemical Soc inc, 2023) Guler, I.
Silicon nitride thin films are very important for their possible use in semiconductor industry and electronic applications. Changing the deposition parameters, silicon nitrides which have many varying optical properties can be produced. In this work, silicon nitride (SiNx) thin films were deposited on silicon substrates using Plasma enhanced chemical vapor deposition (PECVD) technique. The silane (SiH4) and ammonia (NH3) were used as reactant gases. Using these reactant gases, nitrogen (N) rich SiNx films were obtained. In order to get information about absorption and bond types in the films, films were analyzed by the help of Fourier transform infrared spectroscopy (FTIR) was performed. The refractive index, extinction coefficient and band gap energy of the films were changed from 1.86, 0 and 5.38 eV to 2.05, 0.0048 and 4.26 eV, respectively. Using the refractive index, composition of the films were estimated that is [N]/[Si] ratio of the films varied from 1.38 to 1.62. For possible applications of the SiNx films, learning the origin of the light-emission of the films is very important so the photoluminescence (PL) measurements were also used to see the luminescent of the SiNx films which is related to the electronic transitions between the K-center level and the conduction band tail states.
Citation - WoS: 5
Citation - Scopus: 5
Determination of Trapping Parameters of Tl2in2s3se Layered Single Crystal by Thermoluminescence
(Wiley-v C H verlag Gmbh, 2018) Gasanly, Nizami; Guler, Ipek
Thermoluminescence (TL) measurements are performed to evaluate the trap states in Tl2In2S3Se layered single crystals. TL experiments are conducted with varying temperature from 10 to 300 K and warming rates from 0.2 to 1.0 K s(-1). From the analysis of both initial rise and curve fitting methods, the activation energy of the traps is obtained as 23 meV. The Chen's method is also used to find activation energy. By means of this technique, the activation energy of the TL glow curve is calculated as 25 meV. From both Chen's method and curve fitting method, the existence of mixed order of kinetics in Tl2In2S3Se crystal is found. The cross section to capture of the trap center is found out from the results of curve fitting method. The trap distribution of the crystals is investigated with different temperatures of illumination at a constant warming rate of 0.8 K s(-1). The temperatures of illumination change from 10 to 22 K. As a result of the increase in temperatures of illumination, the peak maximum values move to higher temperatures and intensity of the TL curves decreases. This behavior shows us that quasicontinuous traps distribution is present in Tl2In2S3Se layered single crystals.
Citation - Scopus: 1
Inference of Autoregressive Model With Stochastic Exogenous Variable Under Short-Tailed Symmetric Distributions
(Springer international Publishing Ag, 2018) Bayrak, Ozlem Tuker; Akkaya, Aysen Dener
In classical autoregressive models, it is assumed that the disturbances are normally distributed and the exogenous variable is non-stochastic. However, in practice, short-tailed symmetric disturbances occur frequently and exogenous variable is actually stochastic. In this paper, estimation of the parameters in autoregressive models with stochastic exogenous variable and non-normal disturbances both having short-tailed symmetric distribution is considered. This is the first study in this area as known to the authors. In this situation, maximum likelihood estimation technique is problematic and requires numerical solution which may have convergence problems and can cause bias. Besides, statistical properties of the estimators can not be obtained due to non-explicit functions. It is also known that least squares estimation technique yields neither efficient nor robust estimators. Therefore, modified maximum likelihood estimation technique is utilized in this study. It is shown that the estimators are highly efficient, robust to plausible alternatives having different forms of symmetric short-tailedness in the sample and explicit functions of data overcoming the necessity of numerical solution. A real life application is also given.
Citation - WoS: 3
Citation - Scopus: 7
Modeling of Infographic Generation Process as a Learning Strategy at the Secondary School Level Based on the Educational Design Research Method
(Turkish Education Assoc, 2018) Akkoyunlu, Buket; Kibar, Pinar Nuhoglu
The study aimed to model an infographic design process for the use of infographics as a learning strategy at the secondary school level. A progressive model was suggested in line with a hypothetical perspective regarding the infographic generation process in order to enable learners to resolve and visualize complex information. Using educational design research methodology, the research took place over three meso cycles each comprised of micro cycles: the first two meso cycles included the micro-cycles of analysis and exploration, design and construction and evaluation and reflection and the third meso cycle the evaluation and reflection micro cycle. The study was conducted in collaboration with Information Technology, Science and Technology and Visual Arts teachers and with the participation of 18 7th grade students in the first meso cycle and 19 7th-grade students in the second meso cycle. The infographic design process and the reached infographic design levels were evaluated using the infographic design rubric, reflection forms and focus group interview. Based on the evaluation results obtained at the end of the first two meso cycles, the infographic design process was redesigned and developed. The infographic design process was designed to include the steps of content acquisition, infographic design information, content preparation, content generation, visual design generation, draft generation and digital design in the first meso cycle. In accordance with evaluations, the second meso cycle preserved these steps and implemented a spiral structure to replace the progressive structure of the first meso cycle. Sub-stages were added to meet the determined needs to the infographic design process, training activities were increased and a greater length of time was given for the digital design step. In accordance with the reflection obtained throughout the process, laboratory computers used in the design process in the first cycle were replaced with the students' own tablets in the second. The infographic design levels and reflections reached in the second meso cycle indicated that the arrangements made in the infographic design process developed the process. At the end of the comprehensive evaluation undertaken in the third meso cycle, a conclusion was reached that the collaboration between different fields, infographic design experience and the use of learners' own instruments was significant. This study can be distinguished from other relevant studies as it presents a comprehensive process model in accordance with the educational design research method which contains applications within itself regarding the implementation of infographic design strategy in the learning process.
Citation - WoS: 3
Citation - Scopus: 3
N-Phosphorylation of Pyrroles: an Intramolecular Migration Reaction
(Pergamon-elsevier Science Ltd, 2018) Unaleroglu, Canan; Tasgin, Dilek Isik
A new synthetic method is reported for the N-phosphorylation of pyrroles via intramolecular migration of a phosphonate diester group. The reaction proceeds under mild conditions and produces N-phosphorylated pyrrole derivatives in moderate to good yields. (C) 2018 Elsevier Ltd. All rights reserved.
Citation - WoS: 9
Optical Analysis of Tlins2xse2(1-X) Mixed Crystals
(Amer inst Physics, 2014) Guler, I.
The ellipsometry measurements were carried out on TlInS2xSe2(1-x) mixed crystals in the spectral range of 1.5-6.0 eV at room temperature. The refractive index, extinction coefficient, real and imaginary parts of dielectric function were found as a result of ellipsometric measurements. The energies of interband transitions (critical point energies) of the TlInS2xSe2(1-x) mixed crystals were obtained by means of the second derivative of the real and imaginary parts of dielectric function. The variation of the critical point energies with the isomorphic anion substitution that is sulfur for selenium atoms was established. (C) 2014 AIP Publishing LLC.
Pyrrolizine-3 Synthesis and Evaluation of Photophysical Properties
(Taylor & Francis inc, 2024) Tasgin, Dilek Isik; Bayraktar, Irem
We describe a synthetic approach for pyrrolizine-3-one derivatives and their photophysical properties. These compounds are prepared by a series of reactions employing the substituted pyrroles in one-pot, two-step oxidation, and intramolecular cyclization processes. The photophysical properties of the synthesized compounds were studied by using UV-Vis and fluorescence spectroscopy in different solvents. Maximum absorbance peaks were observed around 306-416 nm and maximum fluorescence emission around 603-614 nm and 465-498 nm for pyrrolyl and N-methyl pyrrolyl substituents, respectively. The introduction of a pyrrolyl substituent had a significant impact on the Stokes shifts (192-206 nm) and quantum yield values ranged from 0.002 to 0.046.
Citation - WoS: 5
Citation - Scopus: 6
Structural and Optical Properties of Thermally Annealed Thallium Indium Disulfide Thin Films
(Elsevier Science Sa, 2020) Gasanly, N.; Guler, I
Structural and optical properties of thallium indium disulfide (TlInS2) thin films, deposited by thermal evaporation technique and thermally annealed at different temperatures, were analyzed. Crystallite size, dislocation density and lattice strain of the thin films were found from X-ray diffraction experiments. The atomic compositions of the films were determined from energy dispersive spectroscopy analysis. Surface morphology of the films was analyzed using atomic force microscopy. From room temperature transmittance spectrum, the band gap energies of the films were identified. The decrease in band gap energies of the films with the annealing temperature up to 300 degrees C was observed due to increase in crystallite size and decrease in lattice strain. From Raman measurements, it was observed that the Raman shifts of the films were well correlated with those of TlInS2 bulk crystal.
Citation - WoS: 8
Citation - Scopus: 8
A Theoretical Investigation: Effect of Structural Modifications on Molecular, Electronic, and Optical Properties of Phosphonate Substituted Bodipy Dyes
(Wiley-v C H verlag Gmbh, 2021) Tasgin, Dilek Isik; Sirin, Pinar Seyitdanlioglu
Phosphonates are important organophosphorus compounds which exhibit versatile properties in organic chemistry, medicinal chemistry, materials and biological applications. Phosphonate groups have appeared in a very few examples of BODIPY (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) compounds that are important florescent dyes in these areas. The deficiency in the area motivated us to investigate how the phosphonate substituent(s) affect the structural, electronic, and optical properties of meso, alpha, or alpha, alpha '-substituted BODIPYs using density functional theory (DFT) and time-dependent density functional theory (TD-DFT) methods. We have identified the suitable method as HSEH1PBE functional in combination with the basis set 6-31+G** by comparing the theoretical results with the experimental studies. Structural, electronic and optical parameters of a series of designed phosphonate substituted 12 BODIPYs (1-4) have been investigated. The alpha, and alpha, alpha '-vinyl phosphonate substituted BODIPYs (3,4) compared to meso-substituted BODIPYs (1,2) have both lower HOMO/LUMO electronic energies [(-5.57)-(-6.19)/(-3.16)-(-3.91)] and lower electronic energy gaps (E-gap) (2.11-2.42). Electrostatic potential analysis was performed for all BODIPYs to characterize their electron distribution and TD-DFT analysis was used for the absorption spectral analysis. The presented theoretical approach can be a practical guide for experimental studies for the design of new BODIPY compounds with desired properties.

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