Fizik Bilim Dalı

Permanent URI for this collectionhttps://hdl.handle.net/20.500.12416/1819

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Subject: search.filters.subject.Relaxation Time

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Now showing 1 - 6 of 6
  • Article
    Citation - WoS: 8
    Citation - Scopus: 9
    Damping Constant (Linewidth) and the Relaxation Time of the Brillouin La Mode for the Ferroelectric-Paraelectric Transition in Pbzr1-Xtixo3
    (Ieee-inst Electrical Electronics Engineers inc, 2016) Kiraci, Ali; Yurtseven, Hamit
    The damping constant (linewidth) of the longitudinal acoustic (LA) mode is calculated as a function of temperature using the observed Brillouin frequencies of this mode from the literature for the ferroelectric-paraelectric transition (T-C = 657 K) in PbZr1-xTixO3 (x = 0.45). For this calculation of the damping constant, the pseudospin-phonon coupled model and the energy fluctuation model are used by fitting to the observed data for the Brillouin frequencies of the LA mode in the ferroelectric (T < T-C) and paraelectric (T > T-C) phases of this compound (x = 0.45). Values of the activation energy are deduced for both ferroelectric and paraelectric phases. The relaxation time is also obtained by means of fitting to the observed data from the literature for the inverse relaxation time at various temperatures in the paraelectric phase of PbZr1-xTixO3. The temperature dependences of the damping constant and of the relaxation time with the values of the activation energy that we have calculated indicate that the pseudospin-phonon coupled model and the energy fluctuation model are capable of describing the ferroelectric-paraelectric transition (T-C = 657 K) in PbZr1-xTixO3 (x = 0.45) adequately.
  • Article
    Citation - WoS: 11
    Citation - Scopus: 12
    Temperature Dependence of the Damping Constant and the Relaxation Time Close To the Tetragonal-Cubic Phase Transition in Srzro3
    (Elsevier Science Bv, 2017) Kiraci, A.; Yurtseven, H.
    The damping constant Gamma(sp) due to the pseudospin-phonon coupling is calculated as a function of temperature using the pseudospin-phonon coupled model and the energy fluctuation model close to the tetragonal-cubic transition (T-C = 1443 K) in SrZrO3. Using the observed Raman frequencies and the linewidth (FWHM) of the soft modes (E-g and A(1g)) from the literature, predictions of both models studied, are examined for the tetragonal-cubic transition in this crystalline system. Values of the activation energy U are extracted and also the inverse relaxation time is predicted as a function of temperature close to the phase transition studied in SrZrO3. Divergence behaviour of the damping constant (FWHM) of the soft modes is predicted from both models as also observed experimentally when T-C is approached from the tetragonal to the cubic phase in SrZrO3. The relaxation time also diverges close to the T-C in this crystal. It is indicated that the tetragonal cubic transition is of a second order as predicted from both models studied here, as also observed experimentally in SrZrO3. (C) 2016 Elsevier B.V. All rights reserved.
  • Article
    Citation - WoS: 5
    Citation - Scopus: 5
    Temperature Dependence of the Polarization, Dielectric Constant, Damping Constant and the Relaxation Time Close To the Ferroelectric-Paraelectric Phase Transition in Linbo3
    (Elsevier Gmbh, Urban & Fischer verlag, 2017) Yurtseven, H.; Kiraci, A.
    We calculate the order parameter (spontaneous polarization) and the inverse dielectric susceptibility at various temperatures in the ferroelectric phase of LiNbO3 for its ferroelectric-paraelectric phase transition (T-C =1260 K) using the Landau phenomenological model. For this calculation, the Raman frequencies of the soft optic mode (TO1) are used as the order parameter and the fitting procedure is employed for both the order parameter and the inverse dielectric susceptibility by means of the observed data from the literature. The temperature dependences of the damping constant and the inverse relaxation time are also computed using the pseudospin-phonon coupled model and the energy fluctuation model for the ferroelectric phase of LiNbO3. The activation energy is deduced from the damping constant for both models studied and compared with the k(B)T(C) value of LiNbO3. We find that the order parameter (Raman frequency of the TO1 mode) and the inverse dielectric susceptibility decrease with increasing temperature, as expected from the mean field model. We also find that the damping constant and the inverse relaxation time of this soft mode increases and decreases, respectively, with increasing temperature on the basis of the two models studied in the ferroelectric phase of LiNbO3. This indicates that our method of calculation is satisfactory to describe the observed behaviour of the ferroelectric-paraelectric phase transition in LiNbO3. (C) 2016 Elsevier GmbH. All rights reserved.
  • Article
    Citation - WoS: 4
    Citation - Scopus: 5
    Calculation of the Raman Frequency, Damping Constant (Linewidth) and the Relaxation Time Near the Tetragonal-Cubic Transition in Pbtio3
    (Elsevier Gmbh, 2017) Yurtseven, H.; Kiraci, A.
    Frequencies, damping constants and the relaxation times of some Raman modes including the two soft modes are calculated as a function of pressure near the tetragonal-cubic transition in PbTiO3. Calculation of the Raman frequencies is performed using the observed volume data from the literature by means of the mode Gruneisen parameter at various pressures. Pressure dependence of the damping constant and the relaxation time is predicted using the pseudospin-phonon coupled model and the energy fluctuation model by considering that the Raman frequency can be taken as the order parameter (spontaneous polarization) for the tetragonal-cubic transition in PbTiO3. Expressions from both models for the damping constants are fitted to the observed Raman linewidths of the two soft modes and for the other Raman modes the damping constant and the relaxation time are predicted close to the transition. We find that damping constants diverge and the inverse relaxation time decreases for the soft modes with increasing pressure near the critical pressure (P-c similar to 11 GPa). The other Raman modes exhibit unusual critical behavior. Our results indicate that the observed behavior of the Raman frequencies can be predicted from the volume data through the mode Gruneisen parameter for the tetragonal-cubic transition in PbTiO3. The damping constant and the relaxation time for the Raman modes can also be predicted adequately using the pseudospin-phonon coupled model and the energy fluctuation model to explain the mechanism of the phase transition between the tetragonal and cubic phases in PbTiO3. (C) 2017 Elsevier GmbH. All rights reserved.
  • Article
    Calculation of the raman frequency, damping constant (Linewidth) and the relaxation time near the tetragonal-cubic transition in PbTiO3
    (Elsevier GMBH, 2017) Kiracı, Ali; Yuetseven, Hamit; Yurtseven, H.
    Frequencies, damping constants and the relaxation times of some Raman modes including the two soft modes are calculated as a function of pressure near the tetragonal-cubic transition in PbTiO3. Calculation of the Raman frequencies is performed using the observed volume data from the literature by means of the mode Gruneisen parameter at various pressures. Pressure dependence of the damping constant and the relaxation time is predicted using the pseudospin-phonon coupled model and the energy fluctuation model by considering that the Raman frequency can be taken as the order parameter (spontaneous polarization) for the tetragonal-cubic transition in PbTiO3. Expressions from both models for the damping constants are fitted to the observed Raman linewidths of the two soft modes and for the other Raman modes the damping constant and the relaxation time are predicted close to the transition. We find that damping constants diverge and the inverse relaxation time decreases for the soft modes with increasing pressure near the critical pressure (P-c similar to 11 GPa). The other Raman modes exhibit unusual critical behavior. Our results indicate that the observed behavior of the Raman frequencies can be predicted from the volume data through the mode Gruneisen parameter for the tetragonal-cubic transition in PbTiO3. The damping constant and the relaxation time for the Raman modes can also be predicted adequately using the pseudospin-phonon coupled model and the energy fluctuation model to explain the mechanism of the phase transition between the tetragonal and cubic phases in PbTiO3
  • Article
    Citation - WoS: 2
    Citation - Scopus: 3
    Analysis of the Integrated Intensity of the Central Peaks Calculated as a Function of Temperature in the Ferroelectric Phase of Lithium Tantalate
    (Vinca inst Nuclear Sci, 2018) Yurtseven, Hamit; Kiraci, Ali
    The integrated intensity of the central peak is calculated as a function of temperature in the ferroelectric phase (T < T-C) of nearly stoichiometric LiTaO3. This calculation is performed using the temperature dependence of the order parameter obtained from the mean field theory at temperatures lower than the transition temperature T-C (T-C = 963 K) of this crystal. The calculated values of the order parameter (squared) are fitted to the integrated intensity of the central peaks as observed from the Raman and Brillouin scattering experiments as reported in the literature in the ferroelectric phase of nearly stoichiometric LiTaO3. Our results are in good agreement with the observed behavior of LiTaO3 crystal. Because of the applications of LiTaO3 in several academic disciplines including the material science and thermal science, it is beneficial to investigate dynamic properties of this crystal such as the damping constant, inverse relaxation time and the activation energy as also we studied here.